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A library of dimeric CD1d ligands, containing two α-galactosyl ceramide (α-GalCer) units linked by spacers of varying lengths has been synthesised. The key dimerisation reactions were carried out via copper-catalysed click reactions between a 6″-azido-6″-deoxy- α-galactosyl ceramide derivative and various diynes. Each α-GalCer dimer was tested for its ability to stimulate iNKT cells. © 2012 Elsevier Ltd. All rights reserved.

Original publication

DOI

10.1016/j.carres.2012.02.034

Type

Journal article

Journal

Carbohydrate Research

Publication Date

15/07/2012

Volume

356

Pages

152 - 162